Product ID:PHENOSEAL VINYL ADHESIVE CAULK, SERIES 100
MSDS Date:04/07/1997
FSC:8040
NIIN:00N026899
Status Code:A
MSDS Number: CJQNZ

GLOUCESTER CO INC

235 COTTAGE ST
FRANKLIN, MA 02038
US

Emergency Phone: 508-528-2200

Info Phone: 508-528-2200

Preparer: LAWRENCE H. BOISE

Cage: 0BXJ1

GLOUCESTER CO INC

428 FRANKLIN, MA 02038 US

Telephone: 508-528-2200

Cage: 0BXJ1

VINYL ACETATE MONOMER

CAS: 108-05-4

RTECS: AK0875000

OSHA PEL 10 PPM TWA

ACGIH TLV: 35 MG/M3;10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

N-BUTYL ACETATE

CAS: 123-86-4

RTECS: AF7350000

OSHA PEL 710 MG/M3;150 PPM

ACGIH TLV: 713 MG/M3;150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPYLENE GLYCOL

CAS: 57-55-6

RTECS: TY2000000

2,2,4-TRIMETHYL-1,3-PENTANEDIOL MONOISOBUTYRATE

CAS: 25265-77-4

RTECS: UF6000000

3,3'-OXYDI-1-PROPANOL DIBENZOATE

CAS: 27138-31-4

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: DIRECT CONTACT CAN CAUSE
IRRITATION. SKIN: MAY CAUSE TEMPORARY IRRITATION.
Explanation of Carcinogenicity:VINYL ACETATE IS IDENTIFIED BY IARC AS A
POTENTIAL CARCINOGEN, 2B, POSSIBLY CARCINOGENIC TO HUMANS (BASED ON
INADEQUATE HUMAN DATA AND LIMITED ANIMAL DATA).
Effects of Overexposure:IRRITATION TO EYES, SKIN OR RESPIRATORY TRACT.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS MAY BE MORE SUSCEPTIBLE TO IRRITATING EFFECTS.

First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. SKIN:
IMMEDIATELY WASH AFFECTED AREAS THOROUGHLY WITH SOAP AND WATER.
INGESTION: C ONSULT MD. INHALATION: REMOVE TO FRESH AIR.

Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:DIRED POLYMER FILMS ARE CAPABLE OF
BURNING. MATERIAL MAY SPLATTER IF TEMPERATURES EXCEED BOILING POINT
(212F).

Spill Release Procedures:KEEP SPILLS AND CLEANING RUNOFF OUT OF
MUNICIPAL SEWERS AND OPEN BODIES OF WATER. TRANSFER LIQUIDS AND
SOLID DIKING MATERIAL TO SEPARATE SUITABLE CONTAINERS FOR RECOVERY
OR DISPOSAL.

Handling and Storage Precautions:KEEP MATERIAL FROM FREEZING.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.

Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NO SPECIAL REQUIREMENTS UNDER NORMAL USE AND
CONDITIONS.
Ventilation:LOCAL EXHAUST; MECHANICAL (OTHER); ROOM VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . USE
OTHER PROTECTIVE CLOTHING OR EQUIPMENT AS APPROPRIATE TO PREVENT
PROLONGED OR REPEATED CONTACT WITH SKIN.
Work Hygienic Practices:WASH THORO AFTER HANDLING. USE GOOD PERSONAL
HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING, SMOKING OR
USING RESTROOM FACILITIES. PROMPTLY REMOVE CONTAM CLOTHING &
LAUNDER THORO BEFORE REUSE.
Supplemental Safety and Health

Boiling Pt:=100.C, 212.F
B.P. Text:WATER
Melt/Freeze Pt:=0.C, 32.F
M.P/F.P Text:WATER
Vapor Pres:NOT DETERMINED
Vapor Density:HVR/AIR
Spec Gravity:1.1-1.3 (WATER=1)
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:DILUTABLE
Appearance and Odor:MILKY (OR COLORED) AQUEOUS PASTE.
Percent Volatiles by Volume:40 (BY WT)

Stability Indicator/Materials to Avoid:YES
MATERIALS THAT REACT WITH WATER.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:WHEN EXPOSED TO FIRE, PRODUCES NORMAL
PRODUCTS OF COMBUSTION.

Waste Disposal Methods:OBSERVE ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.

Toxicological Information:AVAILABLE EPIDEMIOLOGICAL STUDIES DO NOT
CONFIRM AN INCREASED RISK OF CANCER IN EXPOSED HUMANS; AVAILABLE
EVIDENCE SUGGESTS THAT VINYL ACETATE IS NOT LIKELY TO CAUSE CANCER
IN HUMANS EXCEPT UNDER UNCO MMON OR UNLIKELY ROUTES OR LEVELS OF
EXPOSURE (ACGIH, ANIMAL CARCINOGEN, A3).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 TITLE III REQUIRES SUBMISSION OF ANNUAL REPORTS OF
RELEASE OF TOXIC CHEMICALS THAT APPEAR IN 40 CFR 372 (OR SARA 313).
THIS PRODUCT CONTAINS TH E FOLLOWING CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). CHEMICAL (CAS NO;
% BY WT): NONE ABOVE DEMINI MIS REPORTING LEVEL.
Federal Regulatory Information:TESTS BY AN INDEPENDENT LABORATORY
ACCORDING TO THE TOXIC SUBSTANCES CONTROL ACT (TSCA) INDICATE THAT
THE MIXTURE IS NON-TOXIC ACCORDING TO ACUTE ORAL TOXICITY TESTS 40
CFR 798.1175 AND A NON-IRRITANT TO OCCULAR TISSUE ACCORDING TO 40
CFR 798.4500. IT IS CONSIDERED A SKIN IRRITANT ACCORDING TO
PROCEDURES OUTLINED IN 40 CFR 798.4470. THIS MSDS IS PREPARED
PURSUANT TO THE OSHA HAZARDOUS COMMUNICATIO N STANDARD (29 CFR
1910.1200).